Diaqua[N-(5-nitro-2-oxidobenzylidene)glycinato]copper(II) dihydrate
نویسندگان
چکیده
In the title complex, [Cu(C(9)H(6)N(2)O(5))(H(2)O)(2)]·2H(2)O, the Cu(II) atom has a square-pyramidal coordination environment with a tridentate N-(5-nitro-2-oxidobenzyl-idene)glycinate Schiff base ligand and a water mol-ecule in the basal plane. The apical site is occupied by an O atom from another coordinated water mol-ecule. The crystal structure is stabilized by O-H⋯O hydrogen bonds, building a two-dimensional network parallel to (100).
منابع مشابه
{2-[(5-Bromo-2-oxidobenzylidene)amino-κ2 N,O]-3-methylpentanoato-κO}(1,10-phenanthroline-κ2 N,N′)copper(II) dihydrate
In the title compound, [Cu(C(13)H(14)BrNO(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is penta-coordinated in a square-pyramidal geometry. The crystal packing is stabilized by O-H⋯O hydrogen bonds.
متن کاملTriaquabis{μ-N-[N-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate
In the title compound, [CdCu(2)(C(12)H(11)N(2)O(5))(2)(H(2)O)(3)]·2H(2)O, the Cu(II) atoms are in a square plane of N(2)O(2) atoms contributed by the tetra-dentate Schiff base trianion. The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxyl-ate O atom. The Cd(II) atom is connected via the carboxyl-ate groups, forming a heterotrinuclear Cu(I...
متن کاملDiaqua(1,4,8,11-tetraazacyclotetradecane-κ4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate
The Cu(II) atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)·2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetra-aza-cyclo-tetra-decane (cyclam) ligand and is coordinated by two water mol-ecules in a Jahn-Teller-type tetra-gonally distorted octa-hedral geometry. The Cu(II) atom lies on a center of inversion. The cations, anions and uncoordinated water mol-ecules...
متن کامل{2-(4-Hydroxyphenyl)-2-[(3-methoxy-2-oxidobenzylidene)amino-κ2 O 2,N]propanoato-κO}(1,10-phenanthroline-κ2 N,N′)copper(II) dihydrate
In the title complex, [Cu(C(17)H(15)NO(5))(C(12)H(8)N(2))]·2H(2)O, the central Cu(II) ion is five-coordinate, bound to one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal configuration. In the crystal, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds form a two-dimensional network parallel to (001).
متن کاملDiaqua(5-methyl-1H-pyrazole-3-carboxylato)(4-nitrobenzoato)copper(II)
In the title complex, [Cu(C(7)H(4)NO(4))(C(5)H(5)N(2)O(2))(H(2)O)(2)], the Cu(II) ion is coordinated in a slightly distorted square-pyramidal enviroment. The basal plane is formed by an N atom and an O atom from a 5-methyl-1H-pyrazole-3-carboxyl-ate ligand and by two O atoms from two water ligands. The apical position is occupied by a carboxylate O atom from a 4-nitro-benzoate ligand. In the cr...
متن کامل